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DEPARTMENT OF CHEMISTRY
INDIAN INSTITUTE OF TECHNOLOGY MADRAS
CY7210 : Advanced Solid State Chemistry
Crystal Chemistry:
Introduction, detailed description of structures of complex oxides and related compounds, Phillips ionicity and crystal chemistry; Structural interrelations .
Defects:
Origin of defects; Types of defects – equilibrium, nonequilibrium, point, line, planar, nonstoichiometry, Wadsley defect; Experimental methods of investigating defects in solids; Dislocations, grain boundaries etc. Defects and physical properties.
Bonding and electron transport:
Atoms to molecules to crystals; Orbitals – bond – bands: Electronic structure of solids, band theory, non metals, metals, metal- nonmetal transitions; Transport properties, techniques, electrical conductivity, thermopower and Hall effect measurements; Chemical approach to bonding in solids; Case studies – Oxides.
Magnetic properties:
Dia, para, ferro, antiferro and ferromagnetism; Magnetism of free electrons; Measurements; Magnetically ordered solids, soft and hard magnetic materials; Case studies – Oxides.
Dielectric and optical properties: Principle and theory;
Standard examples like BaTiO3; Applications.
Phase Transitions:
Classification; Landau’s Theory; Nucleationgrowth,
Martensitic transformations; Examples; Metal-insulator transitions.
Solid state synthesis:
Conventional and novel methods; Specific examples;
Rational synthesis of solids.
Characterization by diffraction
Modern developments:
Superconductivity of oxide materials, C60; Intercalation chemistry etc.
References:
- C.N.R. Rao and J. Gopalakrishnan, New directions in solid state chemistry, Cambridge University Press, London, 1986.
- A.R. West, Solid State Chemistry and its applications, John Wiley, New York 1984.
- L.V. Azaroff, Introduction to Solids, Tata McGraw Hill Publishing Company Ltd., New Delhi, 1990.
- D.M. Adams, Inorganic Solids, John Wiley and Sons, New York, 1974.
- N.N. Greenwood, Ionic Crystals, Lattice Defects, nonstoichiometry, Butterworths, London, 1968.
- C. Kittel, Introduction to solid state physics, JohnWiley and Sons, New York, d1986.
- M. Ali Omar, Elementary solid state physics: Principles and Applications, Addison-Wesley Publishing Company, California, 1975.
- P.A. Cox, The electronic structure and chemistry of solids, Oxford University Press, Oxford, 1987.
- C.N.R. Rao and K.J. Rao, Phase transitions in solids, McGraw Hill Book Co., New York, 1978.
- T.V. Ramakrishna and C.N.R. Rao, Superconductivity today, Wiley- Easter, 1992.
- G. Burns, Solid State Physics, Academic Press, New York, 1985.
- J.M. Hong and C.N.R. Rao, Preparation and characterization of materials, Academic Press, New York, 1981.
